87199-16-4 3-Formylphenylboronic Acid

Synonyms:

3-Formylpenylboronic Acid;Boronic acid,    (3-formylphenyl)- (9CI);3-FORMYLPHENYLBORONIC    ACID (CONTAINS VARYING AMOUNTS OF ANHYDRIDE);3-(Dihydroxyboryl)benzaldehyde,    3-Boronobenzaldehyde;3-Formylphenylboronic    acid,97%;2-bromo-1-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)ethanone;3-Formylphenylboronic acid, May contain varying amounts    of anhydride, 97%;3-Formylphenylboroni

CAS:

87199-16-4

MF:

C7H7BO3

MW:

149.94

EINECS:

Product Categories:

ALDEHYDE;Aldehydes;blocks;BoronicAcids;Boronic Acid series;Boron, Nitrile, Thio,& TM-Cpds;Carbonyl Compounds;Substituted Boronic Acids;Boronic Acids & Esters;Phenyls & Phenyl-Het;Boronic acids;Boronic Acid;Aryl;Organoborons;B (Classes of Boron Compounds);Boronic Acids & Esters;Phenyls & Phenyl-Het;Aryl Boronic Acids;Boronic Acids and Derivatives;Building Blocks;C7;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organic Building Blocks;Organometallic Reagents;Boronate Ester;Potassium Trifluoroborate

Mol File:

87199-16-4.mol

storage temp. 

0-6°C

form 

Powder, Crystals, and/or Chunks

color 

Off-white to beige or light orange

Sensitive 

Air Sensitive

Appearance:

off-white cryst

Density:

1.244g/cm3

Boiling Point:

354.388ºC at 760 mmHg

Flash Point:

168.128ºC

Refractive Index:

1.548

Storage Condition:

0-6ºC

BRN 

3030769

CAS DataBase Reference

87199-16-4(CAS    DataBase Reference)

Risk Statements 

34-36/37/38

Safety Statements 

22-26-36/37/39-45-37/39-27

RIDADR 

UN 3261 8/PG 3

WGK Germany 

3

Hazard Note 

Irritant

HazardClass 

IRRITANT, MOISTURE SENSITIVE

PackingGroup 

Ⅲ

hazard declaration:

H314

HS Code:     

2931900090

Uses

Reagent used: • ;To study the effects of boronic acid on fluoride-selective chemosignaling behavior of merocyanine dye1• ;As exciton-coupled CD probes for epigallocatechin gallate2Biological inhibitor of γ-glutamyltranspeptidase3Reactant involved in: • ;Palladium-catalyzed homocoupling4• ;Suzuki coupling reactions5

Uses

suzuki reaction

Intermediate as

912545-86-9(free base) SAG

Synthesis route

Reference:

Meudt, Andreas; Scherer, Stefan; Vollmueller,    Frank; Erbes, Michael Patent: US2004/49050 A1, 2004

Reference:

TEIJIN LIMITED Patent: EP1460059 A1, 2004 ;    Location in patent: Page 9

Reference:

Arkiv foer Kemi, , vol. 10, p. 507,509

Reference:

Journal of the American Chemical Society, ,    vol. 134, # 28 p. 11667 - 11673

Reference:

Chemical Communications, , vol. 46, # 15 p.    2677 - 2679