3-Formylphenylboronic acid Basic information
Product Name: | 3-Formylphenylboronic acid |
Synonyms: | 3-Formylpenylboronic Acid;Boronic acid, (3-formylphenyl)- (9CI);3-FORMYLPHENYLBORONIC ACID (CONTAINS VARYING AMOUNTS OF ANHYDRIDE);3-(Dihydroxyboryl)benzaldehyde, 3-Boronobenzaldehyde;3-Formylphenylboronic acid,97%;2-bromo-1-(2,3-dihydrobenzo[b][1,4]dioxin-6-yl)ethanone;3-Formylphenylboronic acid, May contain varying amounts of anhydride, 97%;3-Formylphenylboroni |
CAS: | 87199-16-4 |
MF: | C7H7BO3 |
MW: | 149.94 |
EINECS: |
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Product Categories: | ALDEHYDE;Aldehydes;blocks;BoronicAcids;Boronic Acid series;Boron, Nitrile, Thio,& TM-Cpds;Carbonyl Compounds;Substituted Boronic Acids;Boronic Acids & Esters;Phenyls & Phenyl-Het;Boronic acids;Boronic Acid;Aryl;Organoborons;B (Classes of Boron Compounds);Boronic Acids & Esters;Phenyls & Phenyl-Het;Aryl Boronic Acids;Boronic Acids and Derivatives;Building Blocks;C7;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organic Building Blocks;Organometallic Reagents;Boronate Ester;Potassium Trifluoroborate |
Mol File: | 87199-16-4.mol |
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3-Formylphenylboronic acid Chemical Properties
Melting point | 182-186 °C |
storage temp. | 0-6°C |
form | Powder, Crystals, and/or Chunks |
color | Off-white to beige or light orange |
Sensitive | Air Sensitive |
Appearance: | off-white cryst |
Density: | 1.244g/cm3 |
Boiling Point: | 354.388ºC at 760 mmHg |
Flash Point: | 168.128ºC |
Refractive Index: | 1.548 |
Storage Condition: | 0-6ºC |
BRN | 3030769 |
CAS DataBase Reference | 87199-16-4(CAS DataBase Reference) |
Safety Information
Hazard Codes | C,Xi |
Risk Statements | 34-36/37/38 |
Safety Statements | 22-26-36/37/39-45-37/39-27 |
RIDADR | UN 3261 8/PG 3 |
WGK Germany | 3 |
Hazard Note | Irritant |
HazardClass | IRRITANT, MOISTURE SENSITIVE |
PackingGroup | Ⅲ |
hazard declaration: | H314 |
HS Code: | 2931900090 |
3-Formylphenylboronic acid Usage And Synthesis
Chemical Properties | Off-white Cryst |
Uses | Reagent used: • ;To study the effects of boronic acid on fluoride-selective chemosignaling behavior of merocyanine dye1• ;As exciton-coupled CD probes for epigallocatechin gallate2Biological inhibitor of γ-glutamyltranspeptidase3Reactant involved in: • ;Palladium-catalyzed homocoupling4• ;Suzuki coupling reactions5 |
Uses | suzuki reaction |
Intermediate as | 912545-86-9(free base) SAG
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Synthesis route |
Reference:Meudt, Andreas; Scherer, Stefan; Vollmueller, Frank; Erbes, Michael Patent: US2004/49050 A1, 2004
Reference:TEIJIN LIMITED Patent: EP1460059 A1, 2004 ; Location in patent: Page 9
Reference:Arkiv foer Kemi, , vol. 10, p. 507,509
Reference:Journal of the American Chemical Society, , vol. 134, # 28 p. 11667 - 11673
Reference:Chemical Communications, , vol. 46, # 15 p. 2677 - 2679 |
3-Formylphenylboronic acid Preparation Products And Raw materials
Preparation Products | 3-(4-METHYLPHENYL)BENZALDEHYDE |
Upstream information
magnesium compound of 3-(dimethoxymethyl)bromobenzene; 9,10-Dibromoanthracene; 9-Bromoanthracene; 2-Hydroxy-4-iodobenzoic acid; phenol; 2-Amino-3-Chlorothiophenol; 2-Chloropyrimidine; Iodobenzene; tris(3-methylphenyl)-1,3,5,2,4,6-trioxatriborinane; 2-Bromopyrimidine;
Downtream information
3-(2-FURYL)BENZALDEHYDE; 3-Phenylbenzaldehyde; 3-(2-Pyridyl)benzaldehyde; 4-(3-formylphenyl)benzonitrile; 3-(2-Methylnaphthalen-1-yl)benzaldehyde; 3-(3-Methoxypyridin-2-yl)benzaldehyde; {2',6'-Dimethyl-4'-[3-(methylsulfonyl)propoxy]-3-biphenylyl}metha nol; 3-Naphthalen-1-yl-benzaldehyde; 3-Fluorobenzaldehyde; 3-thiophen-2-ylbenzaldehyde;
