99769-19-4 3-Methoxycarbonylphenylboronic Acid

Synonyms:

METHYL 3-BORONOBENZOATE;3-METHOXYCARBONYLPHENYLBORONIC ACID;3-(METHOXYCARBONYL)BENZENEBORONIC ACID;AKOS BRN-0125;M-(METHOXYCARBONYL)PHENYLBORONIC ACID;3-METHOXYCARBONYLPHENYLBARONIC ACID;3-(Methoxycarbonyl)phenylboronic Acid (contains varying amounts of Anhydride);3-Methoxycarbonylphenylboronic acid,97%

CAS:

99769-19-4

MF:

C8H9BO4

MW:

179.97

EINECS:

Product Categories:

blocks;BoronicAcids;Carboxes;Acids and Derivatives;Boron, Nitrile, Thio,&   TM-Cpds;Boronic acids;Aryl;Ester;Organoborons;B (Classes of Boron Compounds);Boronic acid;CHIRAL CHEMICALS;Aromatics;Boron Derivatives;Intermediates & Fine Chemicals;Pharmaceuticals;Boronate Ester;Potassium Trifluoroborate

Mol File:

99769-19-4.mol

color

White to off-white

Appearance:

White to light yellow crystal powder

Density:

1.25g/cm3

Melting Point:

187-191ºC

Boiling Point:

359.9ºC at 760 mmHg

Flash Point:

171.5ºC

Refractive Index:

1.532

Storage Condition:

Refrigerator (+4ºC)

Water Solubility

Reacts with water.

CAS DataBase Reference

99769-19-4(CAS DataBase Reference)

Risk Statements

36/37/38

Safety Statements

37/39-26-36

WGK Germany

3

Hazard Note

Irritant

HazardClass

IRRITANT

Hs code

2931900090

Uses

Used in the preparation of substituted pyrazolylpyrimidinamine derivative for use as protein kinase inhibitors.

Uses

suzuki reaction

Intermediate as

Synthesis route

Reference:

Wang, Xiao-Jun; Sun, Xiufeng; Zhang, Li; Xu, Yibo; Krishnamurthy, Dhileepkumar; Senanayake, Chris H. Organic Letters, 2006 , vol. 8, # 2 p. 305 - 307

Reference:

Journal of the American Chemical Society, vol. 134, # 28 p. 11667 - 11673

Reference:

Organic Letters, vol. 14, # 18 p. 4814 - 4817,4