17933-03-8 (3-methylphenyl)boronic Acid

17933-03-8 (3-methylphenyl)boronic Acid

3-Tolylboronic acid Basic information 3-Tolylboronic acid Chemical Properties Safety Information 3-Tolylboronic acid Usage And Synthesis 3-Tolylboronic acid Preparation Products And Raw materials Upstream information Benzylamine; 4'-Chloroacetophenone; Iodobenzene; phthalaldehyde; Allyl...
Chat Now

Product Details

3-Tolylboronic acid Basic information

Product Name:

3-Tolylboronic acid

Synonyms:

3-Methylphenylboric acid;-Tolylboronic acid;m-Tolylboronicacid,min.97%;M-TOLYBORONICACID;3-METHYLPHENYLBORONIC ACID, 3-TOLYLBORONIC ACID, M-TOLYLBORONIC ACID;3-TOLYLBORONIC ACID 98%;3-Methylphenylboronic Acid (contains varying amounts of Anhydride);Boronic acid, (3-methylphenyl)-

CAS:

17933-03-8

MF:

C7H9BO2

MW:

135.96

EINECS:

-0

Product Categories:

blocks;BoronicAcids;Boronic Acid series;Boron, Nitrile, Thio,& TM-Cpds;Substituted Boronic Acids;Boronic acids;Boronic Acid;Aryl;Organoborons;B (Classes of Boron Compounds);CHIRAL CHEMICALS;organic or inorganic borate;Aryl Boronic Acids;Boronic Acids and Derivatives;Chemical Synthesis;Monosubstituted Aryl Boronic Acids;Organometallic Reagents;Boronate Ester;Potassium   Trifluoroborate

Mol File:

17933-03-8.mol

image001.gif


3-Tolylboronic acid Chemical Properties

form

Powder and Chunks

color

Beige

Appearance:

White - off-white solid.

Density:

1.1 g/cm3

Melting Point:

160-162ºC

Boiling Point:

290.4ºC at 760 mmHg

Flash Point:

129.4ºC

Refractive Index:

1.527

Stability:

Stable under normal temperatures and pressures.

Storage Condition:

0-6ºC

Vapor Pressure:

0.000954mmHg at 25°C

BRN

2935968

CAS DataBase Reference

17933-03-8(CAS DataBase Reference)


Safety Information

Hazard Codes

Xi

Risk Statements

36/37/38

Safety Statements

26-36-37/39

WGK Germany

3

RTECS

ED7788888

Hazard Note

Irritant

HazardClass

IRRITANT

Hs code

2931900090


3-Tolylboronic acid Usage And Synthesis

Chemical Properties

Off-white Crystal

Uses

suzuki reaction

Intermediate as


Synthesis route

image003_副本.jpg

Reference:

Pennington, Thomas E.; Kardiman, Cynantya; Hutton, Craig A. Tetrahedron Letters, 2004 , vol. 45, # 35 p. 6657 - 6660


image005_副本.jpg

Reference:

1. Lloyd, David G.; Hughes, Rosario B.; Zisterer, Daniela M.; Williams, D. Clive; Fattorusso, Caterina; Catalanotti, Bruno; Campiani, Giuseppe; Meegan, Mary J. Journal of Medicinal Chemistry, 2004 , vol. 47, # 23 p. 5612 - 5615

2. Journal of Organic Chemistry, , vol. 67, # 20 p. 7110 - 7123

3. US5183653 A1

4. US5597832 A1, ; US 5597832 A

5. Journal of Organometallic Chemistry, vol. 692, # 20 p. 4244 - 4250


image007_副本.jpg

Reference:

Journal of the American Chemical Society, vol. 132, # 40 p. 14006 - 14008


image009_副本.jpg

Reference:

Journal of the American Chemical Society, vol. 135, # 4 p. 1264 - 1267


3-Tolylboronic acid Preparation Products And Raw   materials

Preparation Products

3-PYRID-2-YLBENZOIC   ACID-->3-CYANOMETHYLPHENYLBORONIC   ACID


Upstream information

Benzylamine; 4'-Chloroacetophenone; Iodobenzene; phthalaldehyde; Allyl bromide; 3-chlorobenzoic acid; acetonitrile; 1-iodo-4-methylbenzene; N-bromosuccinimide; 1,4-benzoquinone;


Downtream information

1-methyl-3-[(3-methylphenyl)disulfanyl]benzene; bis(3-methylphenyl)methanone; 1-benzyl-3-methylbenzene; 4-Formylphenylboronic acid; 3-boronobenzoic acid; (3-methylphenyl)boronic acid; 1-methyl-3-prop-2-enylbenzene; 1-(3-methylcarbazol-9-yl)ethanone; 1-methyl-3-phenylselanylbenzene; 3-(3-Methylphenyl)pyridine


Inquiry